College of Sciences

Chemistry Department

Nathalie A. Wall

Assistant Research Professor

Address

Wahsington State University

Nuclear Radiation Center
Pullman, WA 99164-1300

(509) 335-8917
email: nawall@wsu.edu

Nathalie Wall

Education

  • Doctorate in Sciences (1993), Radioanalytical and Nuclear Chemistry.
    University of Paris XI (Orsay, France). 

  • “Diplôme d'Etudes Approfondies” (DEA) (1990), Radioanalytical and Nuclear Chemistry. 
    University of Paris XI (Orsay, France).
  • “Maîtrise de Sciences Physiques” (1989), Chemistry/Physics. 
    University of Paris XI (Orsay, France). 
  •  These degrees have been certified equivalent to a PhD in Radiochemistry, a MS in Radiochemistry, and a Bachelor in Physics and Chemistry

Research

Prior to joining Washington State University, I worked at the French Commissariat a l'Energie Atomique (Atomic Energy Agency), in the division for the study of nuclear waste repositories; at Florida State University, on a post-doctoral appointment; and at Sandia National Laboratories, studying the Waste Isolation Pilot Plant, the first deep geological repository for transuranic wastes.

My research focuses on the environmental behavior of radio-contaminants, in particular the actinides.  My interest include:

  • the study of the chemical behaviors of inorganic (minerals) and organic (e.g. humic and fulvic acids) colloids,
  • their interaction with the actinides,
  • the evolution of the post-closure chemical environment of a nuclear waste repository,
  • the impact of the repository on the solubility and speciation of actinides. 

I currently study the interaction of actinides with uranyl minerals (boltwoodite, sklodowskite, and uranophane), minerals predicted to form in the vicinity of a nuclear waste repository, upon corrosion of the spent nuclear fuel .

Publications

  • Solubility and Speciation Modeling of Actinides in the Waste Isolation Pilot Plant.  Donald E. Wall, Nathalie A. Wall, and Laurence H. Brush.  In "Separations for the Nuclear Fuel Cycle in the 21st Century", 313-334. Ed. Lumetta et al.  American Chemical Society, Washington, DC (2006).
  • Sustainability of humic acids in the presence of magnesium oxide.  Nathalie A. Wall and Sara A. Mathews.  Applied Geochemistry 20 (9) 1704-1713.  (2005).
  • Humic acids coagulation: influence of divalent cations.  Nathalie A. Wall and Gregory R. Choppin.  Applied Geochemistry, 18, 1573-1582 (2003).  (Also in: Experimental Earth Virtual Journal, 1(3) (2003)).
  • Complexation of americium with humic, fulvic and citric acids at high ionic strength.  N.A. Wall, M. Borkowski, J-F. Chen, G.R. Choppin.  Radiochimica Acta 90, 563-568 (2002).
  • Quality assurance application in nuclear repository research.  Nathalie A. Wall, Laurence H. Brush and Jonathan G. Miller.  GLOBAL 2001 – Proceedings – Paris - France, September 9/13, 2001 (2001).
  • Interaction of actinides with humic and fulvic acids at high ionic strengths. N. Labonne-Wall, G.R. Choppin, C. Lopez and J-M. Monsallier.  In "Actinides Speciation in high ionic strength media", 199 - 211. Ed. Reed et al. Kluwer Academic / Plenum Publishers, New York (1999).
  • Comparison of two models for metal-humic interactions. G.R. Choppin and N. Labonne-Wall.  Journal of Radioanalytical and Nuclear Chemistry 221 (1-2), 67-71 (1997).
  • Retention properties of humic substances onto a mineral oxide: consequences for the sorption of cations.  N. Labonne-Wall, V. Moulin and J-P. Vilarem.  Radiochimica Acta 79, 37-49 (1997).
  • Actinides sorption onto silica in the presence of humic substances: proposal of retention mechanisms.  N. Labonne, V. Moulin and D. Stammose. Material Research Society Proceedings 257, 307-314 (1992).

Jump to...

My Address

My Education

My Research

My Publications

 

Chemistry Department, PO Box 644630, Washington State University, Pullman WA 99164-4630, 509-335-5585, Contact Us